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Conformational isomers

Definition: The different arrangements formed by free rotations about a single bond are
called conformations, and a specific conformation is called a conformer.


In drawing conformations, we often use Newman projections, a way of drawing a molecule looking straight down the bond connecting two carbon atoms.

Dihedral angle θ:- the angle between the C-H bonds on the front carbon atom and the C-H bonds on the back carbon in the Newman projection.

Eclipsed conformation:- Any conformation with bonds directly lined up with each other, one behind the other, in the Newman projection. The conformation with θ = 0o is an eclipsed conformation

Staggered conformation:- Any conformation with the bonds equally spaced in the Newman projection. The conformation with θ = 60° is a staggered conformation.

Torsional strain:- The strain associated with eclipsing of bonds in the ring.

Conformers of butane: CH3-CH2-CH2-CH3

Conformers of butane

Cyclohexane Conformations: The actual structure of cyclohexane.

Cyclohexane Conformations: The actual structure of cyclohexane.
The most stable conformation is the chair conformation.

The most stable conformation is the chair conformation.

The least stable conformation is the boat conformation.

The least stable conformation is the boat conformation.


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